بررسی حذف آنتی بیوتیک فلومکوئین از محیط‌های آبی سنتتیک با استفاده از فرایند US/Fe-doped TiO2

نویسندگان
حسین کمانی 1
رضا رضا حاجی سید محمد شیرازی 2
امیرحسام حسنی 3
1 مرکز ارتقاء سلامت، دانشکده بهداشت، دانشگاه علوم پزشکی زاهدان، زاهدان، ایران
2 گروه منابع طبیعی، واحد علوم و تحقیقات دانشگاه آزاد اسلامی، تهران، ایران
3 دانشکده علوم طبیعی، گروه مهندسی محیط، واحد علوم و تحقیقات دانشگاه آزاد اسلامی، تهران، ایران
چکیده
­مقدمه

در دهه­های اخیر استفاده بیش از حد آنتی بیوتیک­ها در دامپزشکی و پزشکی منجر به ورود این مواد به فاضلاب­ها و در نتیجه آلودگی منابع آب‌های سطحی و زیرزمینی شده است. ورود آنتی­بیوتیک­ها به بدن از طریق آب آشامیدنی می‌تواند عوارض نامطلوبی بر سلامت انسان بگذارد. بنابراین حذف چنین آلاینده‌هایی از منابع آبی ضروری به نظر می‌رسد. بنابراین هدف این مطالعه استفاده از فرآیند اولتراسونیک با Fe-doped TiO2 سنتز شده در آزمایشگاه برای حذف آنتی بیوتیک فلومکوئین از محلول­های آبی می­باشد.

مواد و روش‌­ها

نانوذراتFe-doped TiO2 به روش سل- ژل ساخته شد و آنالیز­های SEM،XRD و DRS برای تعیین خصوصیات آنها استفاده شد. برای بررسی خاصیت سونوکاتالیستی نانوذرات ساخته شده، تاثیر متغیر­های مختلف شامل pH (3-9)، غلظت اولیه فلومکوئین (75-25 میلی­گرم در لیتر)، غلظت نانوذرات ساخته شده (600-200 میلی­گرم در لیتر) و زمان­ واکنش (60-15 دقیقه) برای حذف آنتی بیوتیک فلومکوئین مورد بررسی قرار گرفت.

یافته­‌ها

نتایج حاصل از این پژوهش نشان داد که حداکثر راندمان حذف فلومکوئین 5/96 درصد در شرایط pH برابر 3، غلظت اولیه فلومکوئین 25 میلی­گرم در لیتر و دوز Fe-doped TiO2 برابر 600 میلی­گرم در لیتر در زمان واکنش 60 دقیقه با استفاده از امواج فراصوت با فرکانس ثابت 35 کیلو هرتز بدست آمد.

نتیجه­‌گیری

بنابراین با توجه به راندمان بالای حذف فرآیند سونوکاتالیستی، کاربرد این فرآیند برای حذف آنتی بیوتیک فلومکوئین و سایر آنتی بیوتیک­های مشابه دیگر در صنعت آب و فاضلاب می‌تواند مورد استفاده قرار گیرد.
کلیدواژه‌ها
Fe-doped TiO2
آنتی‌بیوتیک فلومکوئین
سونوکاتالیست
سل –ژل
محیط‌های آبی

عنوان مقاله English

Evaluation of flumequine antibiotic removal from synthetic aqueous media using US / Fe-doped TiO2 process

نویسندگان English

Hossein Kamani 1
Reza Haji Seyed Mohammad Shirazi 2
Amir Hessam Hassani 3
1 Health Promotion Research Center, Zahedan University of Medical Sciences, Zahedan, Iran
2 Department of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran
3 Faculty of Natural Sciences and Environment, Department of Environmental Engineering, Tehran Science and Research Branch, Islamic Azad University, Tehran, Iran
چکیده English

Introduction

The use of antibiotics in veterinary medicine and medical applications has increased widely and the possibility of contamination of water sources with such compounds has increased which causes adverse effects such as increased bacterial resistance and digestive disorders. Therefore, the aim of this study was to use the ultrasonic process with Fe-doped TiO2 nano-particle in the Removal of flumequine.

Materials and Methods

The present study was an experimental-laboratory study conducted as a batch system. nanoparticles were synthesized by the sol-gel method and SEM, XRD, and DRS analyzes were used to determine the properties of nanoparticles. The effect of different variables including pH (3-11), initial concentration of flumequine (25-75 mg/L), and concentration of nanoparticles (200-600 mg/L) at different times (15-60 min) Was examined in sonocatalytic removal of flumequine.

Results

The results of this study showed that the maximum removal efficiency of flumequine was 96.5 % at pH 3, initial concentration of 25 mg/L, and a nanoparticle dose of 600 mg/L, a reaction time of 60 minutes was obtained using ultrasonic waves with a constant frequency of 35 kHz.

Conclusion

Due to the high removal efficiency of sonocatalytic process, the use of this process for the removal of flumequine in water and wastewater treatment processes is recommended.

کلیدواژه‌ها English

Fe-doped TiO2
Sonocatalyst
Flumequine antibiotic
Sol-gel
Aquatic environment
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